Stochastic model of photodynamics in multichromophoric conjugated polymers

被引：12

作者：

Barzykin, AV ^{[1
]}

Tachiya, M ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, AIST, Tsukuba, Ibaraki 3058565, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2006年 / 110卷 / 13期

关键词：

D O I：

10.1021/jp056088q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A stochastic model of triplet exciton dynamics in multichromophoric conjugated polymers is presented and analyzed in detail, with a focus on the single molecule spectroscopy observables. The model deals with the evolution of a discrete statistical distribution of triplets in isolated polymer molecules. This approach should provide more accurate quantitative information on the dynamic processes involved, as compared to the previously used two-state model which assumes that a conjugated polymer cannot contain more than one triplet. In particular, it allows for determination of the triplet-triplet annihilation rate.

引用

页码：7068 / 7072

页数：5

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