Construction of multinuclear heterobimetallic conjugated complex systems

被引：35

作者：

Hirao, T ^{[1
]}

Yamaguchi, S ^{[1
]}

Fukuhara, S ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

SYNTHETIC METALS | 1999年 / 106卷 / 01期

关键词：

pi-conjugated complex; heterobimetallic complex; polyaniline;

D O I：

10.1016/S0379-6779(99)00107-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The controlled complexation of the emeraldine base of poly(o-toluidine) with two different transition metals, Cu(OAc)(2) and Pd(OAc)(2), was achieved in organic solvent to afford the multinuclear heterobimetallic conjugated complexes. The complexation was monitored spectroscopically. [GRAPHICS] The structure was found to depend on the complexation mode. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：67 / 70

页数：4

共 9 条

[1] FUNCTIONALIZED CONDUCTING POLYMERS - TOWARDS INTELLIGENT MATERIALS [J].

GARNIER, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (04) :513-517

[2] Making photoactive molecular-scale wires [J].

Harriman, A ;

Ziessel, R .

CHEMICAL COMMUNICATIONS, 1996, (15) :1707-1716

[3]

Higuchi M, 1996, SYNLETT, P1213

[4] A novel synthetic metal catalytic system [J].

Higuchi, M ;

Ikeda, I ;

Hirao, T .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (04) :1072-1078

[5] Redox behavior of polyaniline-transition metal complexes in solution [J].

Higuchi, M ;

Imoda, D ;

Hirao, T .

MACROMOLECULES, 1996, 29 (25) :8277-8279

[6] A NOVEL REDOX SYSTEM FOR THE PALLADIUM(II)-CATALYZED OXIDATION BASED ON REDOX OF POLYANILINES [J].

HIRAO, T ;

HIGUCHI, M ;

HATANO, B ;

IKEDA, I .

TETRAHEDRON LETTERS, 1995, 36 (33) :5925-5928

[7] Controlled formation of synthetic metal - Transition metal conjugated complex systems [J].

Hirao, T ;

Yamaguchi, S ;

Fukuhara, S .

TETRAHEDRON LETTERS, 1999, 40 (15) :3009-3012

[8] A NOVEL SYNTHETIC METAL CATALYTIC-SYSTEM FOR DEHYDROGENATIVE OXIDATION BASED ON REDOX OF POLYANILINE [J].

HIRAO, T ;

HIGUCHI, M ;

IKEDA, I ;

OHSHIRO, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (02) :194-195

[9]

MacDiarmid A. G., 1987, Conducting Polymers. Special Applications. Proceedings of the Workshop, P105

← 1 →