On the mechanism of alcoholysis of allylic and benzylic alcohols and of epoxides in the presence of ceric ammonium nitrate

被引：15

作者：

Chapuzet, JM ^{[1
]}

Beauchemin, S ^{[1
]}

Daoust, B ^{[1
]}

Lessard, J ^{[1
]}

机构：

[1] UNIV SHERBROOKE,DEPT CHIM,CTR RECH ELECTROCHIM & ELECTROCATALYSE,SHERBROOKE,PQ J1K 2R1,CANADA

来源：

TETRAHEDRON | 1996年 / 52卷 / 12期

关键词：

alcoholysis; allylic and benzylic alcohols; cerium IV;

D O I：

10.1016/0040-4020(96)00076-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The methanolysis of allylic alcohols, benzylic tertiary alcohols and epoxides in the presence of a catalytic amount of eerie ammonium nitrate (CAN) is shown to be catalysed by protons generated from the oxidation of methanol. This reaction is also catalysed by Lewis acids.

引用

页码：4175 / 4180

页数：6

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