Single Chain Folding of Synthetic Polymers by Covalent and Non-Covalent Interactions: Current Status and Future Perspectives

被引：234

作者：

Altintas, Ozcan ^{[1
,2
]}

Barner-Kowollik, Christopher ^{[1
,2
]}

机构：

[1] Karlsruhe Inst Technol, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany

[2] Karlsruhe Inst Technol, DFG Ctr Funct Nanostruct CFN, D-76128 Karlsruhe, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2012年 / 33卷 / 11期

关键词：

intramolecular covalent bonds; hydrogen driven bonding; modular ligation chemistry; natural biomacromolecule mimics; polymeric nanoparticles; single chain self-folding; INTRAMOLECULAR CROSS-LINKING; RADICAL POLYMERIZATION; CLICK CHEMISTRY; BLOCK-COPOLYMERS; NANOPARTICLES; COLLAPSE;

D O I：

10.1002/marc.201200049

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The present feature article highlights the preparation of polymeric nanoparticles and initial attempts towards mimicking the structure of natural biomacromolecules by single chain folding of well-defined linear polymers through covalent and non-covalent interactions. Initially, the discussion focuses on the synthesis and characterization of single chain self-folded structures by non-covalent interactions. The second part of the article summarizes the folding of single chain polymers by means of covalent interactions into nanoparticle systems. The current state of the art in the field of single chain folding indicates that covalent-bond-driven nanoparticle preparation is well advanced, while the first encouraging steps towards building reversible single chain folding systems by the use of mutually orthogonal hydrogen-bonding motifs have been made.

引用

页码：958 / 971

页数：14

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