A practical method for synthesis of terminal 1,2-diols in high enantiomeric excess via oxazaborolidine-catalyzed asymmetric reduction

被引：32

作者：

Cho, BT ^{[1
]}

Chun, YS ^{[1
]}

机构：

[1] Hallym Univ, Dept Chem, Chunchon 200702, Kangwondo, South Korea

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 10期

关键词：

D O I：

10.1016/S0957-4166(99)00184-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric borane reduction of oc-hydroxy ketones protected with a tetrahydropyranyl (THP) group catalyzed by Corey's CBS reagent using N-phenylamine-borane complexes as the hydride source provided the corresponding terminal 1,2-diols with a very high enantiomeric excess. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1843 / 1846

页数：4

共 22 条

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