High oxidation state aqueous organometallics.: Formation and structure of an oxo-centred Cp* MoV trinuclear cation by chemical reduction of Cp*2Mo2O5

被引：21

作者：

Demirhan, F

Gun, J

Lev, O

Modestov, A

Poli, R

Richard, P

机构：

[1] Univ Bourgogne, Fac Sci Gabriel, Lab Synth & Electrosynth Organomet, F-21000 Dijon, France

[2] Celal Bayar Univ, Fac Sci & Liberal Arts, Dept Chem, TR-45030 Muradiye Manisa, Turkey

[3] Hebrew Univ Jerusalem, Fredy & Nadine Hermann Sch Appl Sci, Div Environm Sci, Jerusalem, Israel

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 10期

关键词：

D O I：

10.1039/b203583a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of Cp*2Mo2O5 by zinc/CF3CO2H in MeOH-H2O yields a salt which is composed of [Cp*3Mo3O4 (O2CCF3)(3)](+) and [Zn-2(O2CCF3)(6)](2-) ions after crystallisation from THF-Et2O.

引用

页码：2109 / 2111

页数：3

共 26 条

[1] REACTION OF MOLYBDENUM-MOLYBDENUM TRIPLE BONDED COMPOUNDS WITH GROUP-VIII PEROXO-TRANSITION METAL-COMPLEXES [J].

ARZOUMANIAN, H ;

BALDY, A ;

PIERROT, M ;

PETRIGNANI, JF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 294 (03) :327-331

[2] ORGANOMETALLIC OXIDES - CONVENIENT, HIGH-YIELD SYNTHESES OF THE (PENTAMETHYLCYCLOPENTADIENYL)MOLYBDENUM OXO COMPLEXES (ETA-C5ME5)MOCL(O)2, ANTI-[(ETA-C5ME5)MOCL(O)]2(MU-O), (ETA-C5ME5)MOCL2(O), AND SYN-[(ETA-C5ME5)MO(O)(MU-O)]2 [J].

BOTTOMLEY, F ;

BOYLE, PD ;

CHEN, JH .

ORGANOMETALLICS, 1994, 13 (01) :370-373

[3] ORGANOMETALLIC OXIDES - PREPARATION AND PROPERTIES OF THE CLUSTERS (ETA-C(5)ME(5))(4)MO5O11 AND ([(ETA-C(5)ME(5))MO](3)(MU-OH)(N)(MU-O)(6-N))CL-2 [J].

BOTTOMLEY, F ;

CHEN, JH ;

PRESTON, KF ;

THOMPSON, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) :7989-7995

[4] Preparation and crystal structures of formato complexes of the [MIV3O4]4+ and [MIV3S4]4+ (M = Mo, W) clusters.: Convenient precursors to the corresponding aqua complexes [J].

Brorson, M ;

Hazell, A ;

Jacobsen, CJH ;

Schmidt, I ;

Villadsen, J .

INORGANIC CHEMISTRY, 2000, 39 (07) :1346-1350

[5]

Burnett M.N., 1996, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations

[6] SURVEY OF THE BONDING IN SEVERAL STRUCTURAL TYPES OF TRINUCLEAR MOLYBDENUM AND TUNGSTEN CLUSTER COMPOUNDS [J].

BURSTEN, BE ;

COTTON, FA ;

HALL, MB ;

NAJJAR, RC .

INORGANIC CHEMISTRY, 1982, 21 (01) :302-307

[7] ZINC CARBOXYLATE COMPLEXES - STRUCTURAL CHARACTERIZATION OF SOME BINUCLEAR AND LINEAR TRINUCLEAR COMPLEXES [J].

CLEGG, W ;

LITTLE, IR ;

STRAUGHAN, BP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (06) :1283-1288

[8] CONTRASTING STRUCTURES OF 2 ADDUCTS OF ZINC CROTONATE WITH SUBSTITUTED PYRIDINES [J].

CLEGG, W ;

HUNT, PA ;

STRAUGHAN, BP .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 :613-617

[9] SYNTHESIS AND STRUCTURE OF THE TRIMOLYBDENUM CLUSTER [(CPMOCL)3(MU-CL)4(MU-3-O)] [J].

COLE, AA ;

GORDON, JC ;

KELLAND, MA ;

POLI, R ;

RHEINGOLD, AL .

ORGANOMETALLICS, 1992, 11 (04) :1754-1757

[10]

COLLANGE E, UNPUB NEW J CHEM

← 1 2 3 →