High oxidation state aqueous organometallics.: Formation and structure of an oxo-centred Cp* MoV trinuclear cation by chemical reduction of Cp*2Mo2O5

被引：21

作者：

Demirhan, F

Gun, J

Lev, O

Modestov, A

Poli, R

Richard, P

机构：

[1] Univ Bourgogne, Fac Sci Gabriel, Lab Synth & Electrosynth Organomet, F-21000 Dijon, France

[2] Celal Bayar Univ, Fac Sci & Liberal Arts, Dept Chem, TR-45030 Muradiye Manisa, Turkey

[3] Hebrew Univ Jerusalem, Fredy & Nadine Hermann Sch Appl Sci, Div Environm Sci, Jerusalem, Israel

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 10期

关键词：

D O I：

10.1039/b203583a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of Cp*2Mo2O5 by zinc/CF3CO2H in MeOH-H2O yields a salt which is composed of [Cp*3Mo3O4 (O2CCF3)(3)](+) and [Zn-2(O2CCF3)(6)](2-) ions after crystallisation from THF-Et2O.

引用

页码：2109 / 2111

页数：3

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