Copper(I) salt mediated 1,4-reduction of alpha,beta-unsaturated ketones using hydrosilanes

被引:44
作者
Mori, A
Fujita, A
Nishihara, Y
Hiyama, T
机构
[1] Res. Lab. of Resources Utilization, Tokyo Institute of Technology, Nagatsuta
关键词
D O I
10.1039/a706032g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reduction of alpha, beta-unsaturated ketones with HSiPhMe2 in the presence of CuF(PPh3)(3).2EtOH proceeds in a 1, 4-selective manner to give the corresponding saturated ketones in excellent yields.
引用
收藏
页码:2159 / 2160
页数:2
相关论文
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