1H, 13C, 15N NMR and IR spectroscopic studies of a Rh(II) complex of thiourea

被引：9

作者：

Ahmad, S ^{[1
]}

Isab, AA ^{[1
]}

Ahmad, S ^{[1
]}

机构：

[1] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 56卷 / 18期

关键词：

rhodium acetate; thiourea; NMR; IR; exchange phenomena;

D O I：

10.1080/00958970310001641688

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A rhodium(II) complex of thiourea (Tu), Rh-2(OAc)(4)Tu(2), has been prepared from Rh-2(OAC)(4)(H2O)(2) and characterized. A shift of the nu(N-H) vibration towards higher frequencies in the IR spectrum is consistent with sulfur coordination to rhodium(II). C-13 NMR spectra recorded in DMSO-d(6) reveal that thiourea is replaced by DMSO-d(6) solvent, followed by replacement of acetate ions by free thiourea. N-15 NMR indicates some nitrogen involvement in coordination to form an S-N chelate.

引用

页码：1587 / 1595

页数：9

共 24 条

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