Room-Temperature Arylation of Arenes and Heteroarenes with Diaryliodonium Salts by Photoredox Catalysis

被引：92

作者：

Liu, Yu-Xia ^{[1
,2
]}

Xue, Dong ^{[1
,2
]}

Wang, Jia-Di ^{[1
,2
]}

Zhao, Cong-Jun ^{[1
,2
]}

Zou, Qing-Zhu ^{[1
,2
]}

Wang, Chao ^{[1
,2
]}

Xiao, Jianliang ^{[1
,2
,3
]}

机构：

[1] Shaanxi Normal Univ, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710062, Peoples R China

[2] Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710062, Peoples R China

[3] Univ Liverpool, Liverpool Ctr Mat & Catalysis, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

SYNLETT | 2013年 / 24卷 / 04期

基金：

美国国家科学基金会;

关键词：

arenes; heteroarenes; visible light; aryl radicals; ruthenium; C-H ARYLATION; VISIBLE-LIGHT PHOTOCATALYSIS; BOND-FORMING REACTIONS; METAL-FREE; ALDEHYDES; TRIFLUOROMETHYLATION; PHOTOCHEMISTRY; POLYMERIZATION; ALKYLATION; DISCOVERY;

D O I：

10.1055/s-0032-1318155

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl radicals produced by irradiation of diaryliodonium salts with visible light under the catalysis of [Ru(bpy)(3)](2+) undergo coupling with a wide range of arenes and heteroarenes, affording various biaryls through direct C-H arylation at room temperature.

引用

页码：507 / 513

页数：7

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