Directed Palladium-Catalyzed Oxidative C-H Arylation of (Hetero)arenes with Arylboronic Acids by Using TEMPO

被引：75

作者：

Kirchberg, Sylvia ^{[1
]}

Vogler, Thomas ^{[1
]}

Studer, Armido ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

SYNLETT | 2008年 / 18期

关键词：

biaryls; boronic acids; C-H arylation; nitroxides; palladium;

D O I：

10.1055/s-0028-1083546

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidative Coupling of three different arenes and a thiophene derivative with various arylboronic acids with Pd(OAc)(2) and the commercially available 2,2,6,6-tetramethylpiperidine-N-oxyl radical (TEMPO) as an oxidant are reported. A 2-pyridyl group Oil the Substrates serves as ortho-directing group to mediate the C-H arylation. Mechanistic studies are provided.

引用

页码：2841 / 2845

页数：5

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