Determination of Antimony (III) in Real Samples by Anodic Stripping Voltammetry Using a Mercury Film Screen-Printed Electrode

被引：32

作者：

Dominguez-Renedo, Olga ^{[1
]}

Gomez Gonzalez, M. Jesus ^{[1
]}

Julia Arcos-Martinez, M. ^{[1
]}

机构：

[1] Univ Burgos, Dept Quim, Area Quim Analit, Fac Ciencias, E-09001 Burgos, Spain

来源：

SENSORS | 2009年 / 9卷 / 01期

关键词：

antimony; anodic stripping voltammetry; mercury film electrode; screen-printed; ATOMIC-ABSORPTION-SPECTROMETRY; TRACE DETERMINATION; POTENTIOMETRIC DETERMINATION; PARTICULATE MATTER; L-CYSTEINE; COPPER; SEAWATER; BISMUTH; METALS; WATERS;

D O I：

10.3390/s90100219

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This paper describes a procedure for the determination of antimony (III) by differential pulse anodic stripping voltammetry using a mercury film screen-printed electrode as the working electrode. The procedure has been optimized using experimental design methodology. Under these conditions, in terms of Residual Standard Deviation (RSD), the repeatability (3.81 %) and the reproducibility (5.07 %) of the constructed electrodes were both analyzed. The detection limit for Sb ( III) was calculated at a value of 1.27x10(-8) M. The linear range obtained was between 0.99 x 10(-8) - 8.26 x 10(-8) M. An analysis of possible effects due to the presence of foreign ions in the solution was performed and the procedure was successfully applied to the determination of antimony levels in pharmaceutical preparations and sea water samples.

引用

页码：219 / 231

页数：13

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