Cross-coupling of E,E-1,4-diiodobuta-1,3-diene with nucleophiles catalyzed by Pd or Ni complexes:: a new route to functionalized dienes

被引：23

作者：

Trostyanskaya, IG ^{[1
]}

Titskiy, DY ^{[1
]}

Anufrieva, EA ^{[1
]}

Borisenko, AA ^{[1
]}

Kazankova, MA ^{[1
]}

Beletskaya, IP ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 11期

关键词：

E,E-1,4-diiodobuta-1,3-diene; alkynes; phosphines; phosphonates; palladium and nickel complexes; catalysis;

D O I：

10.1023/A:1015093100084

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

E,E-1,4-Diiodobuta-1,3-diene can enter into cross-coupling reactions with carbon- or other element-centered nucleophiles in the presence of Pd or Ni complexes as catalysts. Convenient procedures were developed for the stereoselective synthesis of E,E-1,4-dialkenylbuta-1,3-dienes, dienyl-1,4-bisphosphonates, E,E-1,4-bis(diphenylphosphino)buta-1,3-diene, E,E-1,4-diphenylbuta-1,3-diene, and E,E-1,4-bis(thiophenyl)buta-1,3-diene.

引用

页码：2095 / 2100

页数：6

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