Probing the mechanism of the Heck reaction with arene diazonium salts by electrospray mass and tandem mass spectrometry

被引：247

作者：

Sabino, AA ^{[1
]}

Machado, AHL ^{[1
]}

Correia, CRD ^{[1
]}

Eberlin, MN ^{[1
]}

机构：

[1] UNICAMP, Inst Chem, BR-13083970 Campinas, SP, Brazil

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 19期

关键词：

Heck reaction; homogeneous catalysis; mass spectrometry; reaction mechanisms; reactive intermediates;

D O I：

10.1002/anie.200353076

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Key ionic intermediates of the Heck reaction of arene diazonium salts have been intercepted and structurally characterized by ESI-MS/MS. The use of electrospray ionization enables the ionic species to be transferred smoothly to the gas phase. A catalytic cycle for this reaction involving all the Pd cationic species intercepted has been proposed (see scheme).

引用

页码：2514 / 2518

页数：5

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