Graphene and its application in fuel cell catalysis: a review

被引:64
作者
Hur, Seung Hyun [1 ]
Park, Jin-Nam [2 ]
机构
[1] Univ Ulsan, Sch Chem Engn & Bioengn, Ulsan 680749, South Korea
[2] Kyungil Univ, Dept New & Renewable Energy, Kyungsan 712701, Kyungsangbuk Do, South Korea
关键词
graphene; PEM fuel cells; catalysts; doping; NITROGEN-DOPED GRAPHENE; ENHANCED ELECTROCATALYTIC ACTIVITY; GRAPHITE OXIDE; ELECTROCHEMICAL CHARACTERIZATION; PERFORMANCE; NANOPARTICLES; STABILITY; SHEETS; NANOSHEETS; FILMS;
D O I
10.1002/apj.1676
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Graphene is considered a promising material for fuel cell vehicles because of its excellent chemical, mechanical, and electrical properties. Recent studies have revealed that using graphene or modified graphene as the catalyst support or as a metal-free catalyst results in significant improvement in the electrocatalytic activity, long term durability, and CO tolerance. This article summarizes both the recent progress of graphene-based fuel cell research and current developments in graphene fabrication processes such as mechanical exfoliation, chemical vapor deposition, and chemical exfoliation. The roles of graphene are also discussed by introducing mechanisms on the basis of theoretical calculations as well as experimental analysis. (c) 2012 Curtin University of Technology and John Wiley & Sons, Ltd.
引用
收藏
页码:218 / 233
页数:16
相关论文
共 109 条
[1]   THE GROTTHUSS MECHANISM [J].
AGMON, N .
CHEMICAL PHYSICS LETTERS, 1995, 244 (5-6) :456-462
[2]   Reduced HOMO-LUMO gap as an index of kinetic stability for polycyclic aromatic hydrocarbons [J].
Aihara, J .
JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (37) :7487-7495
[3]  
[Anonymous], 2002, ASM HDB, P3
[4]   The Potential of Perylene Bisimide Derivatives for the Solubilization of Carbon Nanotubes and Graphene [J].
Backes, Claudia ;
Hauke, Frank ;
Hirsch, Andreas .
ADVANCED MATERIALS, 2011, 23 (22-23) :2588-2601
[5]  
Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/nnano.2010.132, 10.1038/NNANO.2010.132]
[6]   Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[7]   Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics [J].
Berger, C ;
Song, ZM ;
Li, TB ;
Li, XB ;
Ogbazghi, AY ;
Feng, R ;
Dai, ZT ;
Marchenkov, AN ;
Conrad, EH ;
First, PN ;
de Heer, WA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (52) :19912-19916
[8]   Electronic confinement and coherence in patterned epitaxial graphene [J].
Berger, Claire ;
Song, Zhimin ;
Li, Xuebin ;
Wu, Xiaosong ;
Brown, Nate ;
Naud, Cecile ;
Mayou, Didier ;
Li, Tianbo ;
Hass, Joanna ;
Marchenkov, Atexei N. ;
Conrad, Edward H. ;
First, Phillip N. ;
de Heer, Wait A. .
SCIENCE, 2006, 312 (5777) :1191-1196
[9]   Graphene supported electrocatalysts for methanol oxidation [J].
Bong, Sungyool ;
Kim, Yang-Rae ;
Kim, In ;
Woo, Seunghee ;
Uhm, Sunghyun ;
Lee, Jaeyoung ;
Kim, Hasuck .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (01) :129-131
[10]  
Brodie B., 1860, ANN CHIM PHYS, V59, P466