Highly active PdII cyclometallated imine catalyst for the Suzuki reaction

被引:220
作者
Weissman, H [1 ]
Milstein, D [1 ]
机构
[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel
关键词
D O I
10.1039/a906246g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The cyclopalladated, phosphine-free imine complex 1 is an excellent catalyst for the Suzuki cross-coupling, leading to more than 10(5) turnovers with non-activated aryl bromides; the catalyst is air and thermally stable.
引用
收藏
页码:1901 / 1902
页数:2
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