Preparation of covalent-bound iodofullerene through selective opening of fullerene epoxide to form halohydrin fullerene derivatives

被引：14

作者：

Huang, Shaohua

Yang, Xiaobing

Zhang, Xiang

Hu, Xiangqing

Gan, Liangbing ^{[1
]}

Zhang, Shiwei

机构：

[1] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

[2] Beijing Inst Pharmaceut Chem, Beijing 100083, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

[4] State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China

来源：

SYNLETT | 2006年 / 08期

关键词：

fullerene; halohydrin; epoxides; peroxide; Lewis acid;

D O I：

10.1055/s-2006-932462

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The epoxy moiety in a fullerene mixed peroxide can be opened regioselectively by various Lewis acids to form halohydrin fullerene derivatives. The first iodofullerene was obtained by treating the fullerene epoxide with triphenylphosphine and iodine. A single-crystal structure of the chlorohydrin derivative supports the results.

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收藏

页码：1266 / 1268

页数：3

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