Fullerenes as a tert-butylperoxy radical trap, metal catalyzed reaction of tert-butyl hydroperoxide with fullerenes, and formation of the first fullerene mixed peroxides C60(O)(OOtBu)4 and C70(OOtBu)10

被引：169

作者：

Gan, LB ^{[1
]}

Huang, SH

Zhang, XA

Zhang, AX

Cheng, BC

Cheng, H

Li, XL

Shang, G

机构：

[1] Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 45期

关键词：

D O I：

10.1021/ja027714p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

tert-Butylperoxy radicals generated by TBHP and Ru(PPh3)3Cl2 or other catalysts adds to C60 and C70 to form stable multiadducts, C60(O)(OOtBu)4 and C70(OOtBu)10. The four tert-butylperoxy groups in the C60 mixed peroxide are located around a pentagon, and the epoxy O occupies the remaining 6,6-bond connected to the same pentagon. The C70 decaadduct shows an unprecedented C2 symmetry with the 10 tert-butylperoxy groups added around the central part of C70 by consecutive 1,4-addition. The compounds are fully characterized by spectroscopic data. Copyright © 2002 American Chemical Society.

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页码：13384 / 13385

页数：2

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