Insertion of Dioxygen into a Platinum(II)-Methyl Bond To Form a Platinum(II) Methylperoxo Complex

被引：67

作者：

Grice, Kyle A. ^{[1
]}

Goldberg, Karen I. ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 04期

关键词：

C-H BOND; EARLY TRANSITION METALLOCENES; MOLECULAR-OXYGEN; DIMETHYLPLATINUM(II) COMPLEXES; ORGANIC-CHEMICALS; AQUEOUS-SOLUTIONS; CARBON BOND; OXIDATION; ACTIVATION; AUTOXIDATION;

D O I：

10.1021/om8011272

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The platinum(II) complex (PN)PtMe2 (1; PN = 2-((di-tert-butylphosphino)methyl)pyridine) reacts with molecular oxygen in benzene or methylene chloride solutions to form (PN)PtMe(OOMe) (2), a platinum(II) methylperoxo complex. The structure of the methylperoxo species 2 was determined by X-ray crystallography.

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页码：953 / 955

页数：3

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