Photo-degradation of chlorophenols in the aqueous solution

被引：242

作者：

Czaplicka, Marianna ^{[1
]}

机构：

[1] Inst Nonferrous Met, PL-44100 Gliwice, Poland

来源：

JOURNAL OF HAZARDOUS MATERIALS | 2006年 / 134卷 / 1-3期

关键词：

chlorophenols; photo-degradation; kinetic study; mechanisms;

D O I：

10.1016/j.jhazmat.2005.10.039

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The review presents the chlorophenols photo-degradation kinetics and mechanism in the aquatic environment under UV-vis in the presence of hydroxyl radicals and singlet oxygen. The influence of experimental parameters e.g. PH, dissociation degree, presence of oxidants in solution, number and position of Cl atoms on the quantum yield and reaction rate constant of chlorophenols are discussed. Mechanisms of photolysis, reaction with hydroxyl radicals, singlet oxygen and secondary reactions for mono-, di-, tri-, tetra- and pentachlorophenol are proposed. The pathways for intermediate reactions e.g. dechlorination, oxidation, dimerization for chlorophenols are also presented. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：45 / 59

页数：15

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