Synthesis and characterization of copper(I) and copper(II) flavonolate complexes with phthalazine ligand, and their oxygenation and relevance to quercetinase

被引：40

作者：

BaloghHergovich, E

Kaizer, J

Speier, G

机构：

[1] UNIV VESZPREM,DEPT ORGAN CHEM,H-8201 VESZPREM,HUNGARY

[2] HUNGARIAN ACAD SCI,RES GRP PETROCHEM,H-8201 VESZPREM,HUNGARY

来源：

INORGANICA CHIMICA ACTA | 1997年 / 256卷 / 01期

基金：

匈牙利科学研究基金会;

关键词：

copper complexes; flavonolate complexes; phthalazine complexes;

D O I：

10.1016/S0020-1693(39)60540-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper(I) and copper(II) flavonolate (fla) complexes with 1,4-(di-2'-pyridyl) aminophthalazine ligand (PAPH(2)) have been prepared by the reaction of copper salts with flavonol and the ligand in acetonitrile or dichloromethane. The copper(II) centers are bound to the tetradentate phthalazine ligand resulting in both mononuclear and binuclear complexes. Flavonol is oxygenated to the corresponding depside catalyzed by flavonolato copper(II) phthalazine complexes.

引用

页码：9 / 14

页数：6

共 34 条

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