Performance of direct dimethyl ether fuel cells at low temperature

被引:44
作者
Yu, RH
Choi, HG
Cho, SM
机构
[1] Sungkyunkwan Univ, Dept Chem Engn, Suwon 440746, Kyunggi, South Korea
[2] Sungkyunkwan Univ, Dept Syst Management Engn, Suwon 440746, Kyunggi, South Korea
关键词
direct dimethyl ether fuel cell; direct methanol fuel cell; flow field; anode catalyst;
D O I
10.1016/j.elecom.2005.09.023
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The performance of direct dimethyl ether fuel cells (DDMEFC) is presented in this study at the relatively low temperature of 80 degrees C. At temperatures lower than 100 degrees C, since water exists as liquid but DME as a gas, it is difficult for them to use simultaneously as fuel for DDMEFCs even with the low Solubility of DME ill water at atmospheric Pressure. It has been Found that the use or all interdigitated flow field enhances the performance of DDMEFC by facilitating the phase mixing of DME and water. Palladium (Id) catalyst is not nearly electrochemically active to the anode reaction of DDMEFC and platinum-ruthenium (Pt-Ru) catalyst has been found to be effective anode catalysts for DDMEFC at low temperature. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1385 / 1388
页数:4
相关论文
共 8 条
[1]   Performance of dimethyl ether fuel cells using a Pt-Ru catalyst [J].
Haraguchi, T ;
Tsutsumi, Y ;
Takagi, H ;
Tamegai, N ;
Yamashita, S .
ELECTRICAL ENGINEERING IN JAPAN, 2005, 150 (03) :19-25
[2]   Electrocatalytic oxidation of aliphatic alcohols:: Application to the direct alcohol fuel cell (DAFC) [J].
Lamy, C ;
Belgsir, EM ;
Léger, JM .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (07) :799-809
[3]   Direct dimethyl ether polymer electrolyte fuel cells for portable applications [J].
Mench, MM ;
Chance, HM ;
Wang, CY .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (01) :A144-A150
[4]  
MIZUTANI I, IN PRESS J POWER SOU
[5]   Electro-oxidation of dimethyl ether in a polymer-electrolyte-membrane fuel cell [J].
Müller, JT ;
Urban, PM ;
Hölderich, WF ;
Colbow, KM ;
Zhang, J ;
Wilkinson, DP .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (11) :4058-4060
[6]   New fuels as alternatives to methanol for direct oxidation fuel cells [J].
Peled, E ;
Duvdevani, T ;
Aharon, A ;
Melman, A .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (04) :A38-A41
[7]   Direct type polymer electrolyte fuel cells using methoxy fuel [J].
Tsutsumi, Y ;
Nakano, Y ;
Kajitani, S ;
Yamasita, S .
ELECTROCHEMISTRY, 2002, 70 (12) :984-987
[8]   The behavior of palladium catalysts in direct formic acid fuel cells [J].
Zhu, YM ;
Khan, Z ;
Masel, RI .
JOURNAL OF POWER SOURCES, 2005, 139 (1-2) :15-20