Hydrides of the main-group metals: New variations on an old theme

被引：308

作者：

Aldridge, S

Downs, AJ

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

[2] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 11期

关键词：

D O I：

10.1021/cr960151d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The gas-phase studies of transition metal hydrides and their coordination chemistry was presented. The synthesis of the hydrides by addition, metathesis and decomposition and elimination reactions, and the characterization of their physical, thermodynamic and vibrational properties was discussed. The studies also included the chemical aspects of the homolytic and heterolytic cleavage of the metal-hydrogen bonds.

引用

页码：3305 / 3365

页数：61

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