A metal-organic framework containing meso-helical chains: Synthesis, characterization and luminescent property

被引：16

作者：

Ashiry, Kother Osman ^{[1
]}

Zhao, Ya-Hui ^{[1
]}

Shao, Kui-Zhan ^{[1
]}

Su, Zhong-Min ^{[1
]}

Fu, Yao-Mei ^{[1
]}

Hao, Xiang-Rong ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Funct Mat Chem, Changchun 130024, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Bridging ligand; Hydrothermal method; Coordination polymer; X-ray diffraction; Fluorescence;

D O I：

10.1016/j.inoche.2008.06.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new metal-organic frameworks (MOFs), [Cd-3(Pmb)(2)(bpdC)(2)] 2H(2)O (1) (pmb = 3,5-bis(4-pyridylmethylenoxyl)benzoate, bpdc = 2,2'-biphenyldicarboxylate), has been synthesized by hydrothermal method and structurally characterized through IR, TG and single-crystal X-ray analysis. The infinite wave-like 1 D metal-oxygen chains made by Cd3N4O12 clusters in 1 bridged by the carboxylate of bpdc ligand, construct a 21) framework in which interesting meso-helical chains are constructed by metal centers and pmb ligands, Solid state luminescent spectrum of I also has been investigated at room temperature. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1181 / 1183

页数：3

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