Macromolecular materials in heterogeneous catalysis: An aluminium silasesquioxane gel as active catalyst in Diels-Alder reactions of enones

被引：34

作者：

Abbenhuis, HCL ^{[1
]}

vanHerwijnen, HWG ^{[1
]}

vanSanten, RA ^{[1
]}

机构：

[1] EINDHOVEN UNIV TECHNOL,SCHUIT INST CATALYSIS,NL-5600 MB EINDHOVEN,NETHERLANDS

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 16期

关键词：

D O I：

10.1039/cc9960001941

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly active, genuinely heterogeneous catalyst for liquid-phase Diels-Alder reactions of enones results from the silanol centred modification of an incompletely condensed silasesquioxane with trimethylaluminium, the resulting catalytic material being a gel that contains aluminium(III) siloxy functions (Al-O-Si) which are incorporated in a well defined, three-dimensional SiO framework.

引用

页码：1941 / 1942

页数：2

共 13 条

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