Use of hydration and dissociation chemistries with the electrolyte-NRTL model

被引:83
作者
Chen, CC [1 ]
Mathias, PM [1 ]
Orbey, H [1 ]
机构
[1] Aspen Technol Inc, Cambridge, MA 02141 USA
关键词
D O I
10.1002/aic.690450719
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Sound theoretical understanding and accurate mathematical representation of electrolyte solution nonideality were the subject of extensive research efforts for decades. It is demonstrated that these goals can be achieved by incorporation of hydration and partial dissociation chemistries with the semi-empirical electrolyte NRTL model. The resulting model provides a comprehensive thermodynamic framework for accurate correlation and reliable extrapolation of electrolyte solution nonideality over the entire concentration range.
引用
收藏
页码:1576 / 1586
页数:11
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