Tetraazabenzodifluoranthene Diimides: Building Blocks for Solution-Processable n-Type Organic Semiconductors

被引：154

作者：

Li, Haiyan ^{[1
,2
]}

Kim, Felix Sunjoo ^{[1
,2
]}

Ren, Guoqiang ^{[1
,2
]}

Hollenbeck, Emily C. ^{[1
,2
]}

Subramaniyan, Selvam ^{[1
,2
]}

Jenekhe, Samson A. ^{[1
,2
]}

机构：

[1] Univ Washington, Dept Chem Engn, Seattle, WA 98195 USA

[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 21期

基金：

美国国家科学基金会;

关键词：

electron transport; energy conversion; field-effect transistors; semiconductors; solar cells; THIN-FILM TRANSISTORS; CONJUGATED POLYMERS; NAPHTHALENE DIIMIDE; ELECTRON-TRANSPORT; CHANNEL; DESIGN; MOBILITY; PHOTOPHYSICS; PERFORMANCE; OLIGOMERS;

D O I：

10.1002/anie.201210085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

11-Ring heterocyclic diimides were synthesized and found to be planar and to exhibit a slipped face-to-face πstacking. Variation of the substituents tunes the electronic structure and properties. In n-channel organic field-effect transistors, the new organic semiconductors have a high electron mobility. When they were used as acceptor material in polymer solar cells, a power conversion efficiency of 1.8 % was obtained. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5513 / 5517

页数：5

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