Polarised IR-microscope spectra of guanidinium hydrogensulphate single crystal

Polarised IR-microscope spectra of C(NH2)(3)*HSO4 small single crystal samples were measured at room temperature. The spectra are discussed on the basis of oriented gas model approximation and group theory. The stretching vOH vibration of the hydrogen bond with the 0 center dot center dot center dot 0 distance of 2.603 angstrom gives characteristic broad AB-type absorption in the IR spectra. The changes of intensity of the AB bands in function of polariser angle are described. Detailed assignments for bands derived from stretching and bending modes of sulphate anions and ganidinium cations were performed. The observed intensities of these bands in polarised infrared spectra were Correlated with theoretical calculation of directional cosines of selected transition dipole moments for investigated crystal. The vibrational Studies seem to be helpful in understanding of physical and chemical properties of described compound and also in design of new complexes with exactly defined behaviors. (c) 2005 Elsevier B.V. All rights reserved.