A glucose biosensor based on microporous polyacrylonitrile synthesized by single rare-earth catalyst

被引：104

作者：

Zheng, H ^{[1
]}

Xue, HG ^{[1
]}

Zhang, YF ^{[1
]}

Shen, ZQ ^{[1
]}

机构：

[1] Zhejiang Univ, Inst Polymer Sci, Hangzhou 310027, Peoples R China

来源：

BIOSENSORS & BIOELECTRONICS | 2002年 / 17卷 / 6-7期

关键词：

polyacrylonitrile; glucose oxidase; biosensor; enzyme electrode; rare-earth catalyst;

D O I：

10.1016/S0956-5663(02)00010-6

中图分类号：

Q6 [生物物理学];

学科分类号：

071011 ;

摘要：

A glucose biosensor was constructed by electrochemical adsorption of glucose oxidase (GOD) in microporous polyacrylonitrile (PAN), which was synthesized by single rare-earth catalyst-Y(OAr)(3). The biosensor shows a fast response, good operational stability and reproducibility. The influences of molecular weight of polymer, pH, operating potential and temperature on the biosensor response were explored by amperometric method. The apparent activation energy and optimum pH of enzyme-catalyzed reaction are 35.9 kJ mol(-1) and 6.2, respectively. (C) 2002 Elsevier Science BY. All rights reserved.

引用

页码：541 / 545

页数：5

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