Nuclear magnetic resonance visualization of anomalous flow in cone-and-plate rheometry

被引:80
作者
Britton, MM [1 ]
Callaghan, PT [1 ]
机构
[1] MASSEY UNIV,DEPT PHYS,PALMERSTON NORTH,NEW ZEALAND
关键词
D O I
10.1122/1.550846
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
We demonstrate the use of nuclear magnetic resonance (NMR) microscopy to image the velocity distribution for fluids sheared within the gaps (4 degrees and 7 degrees) of cone-and-plate rheometers. These measurements employ a specially constructed rheogoniometer, which fits within the NMR probe system. While the uniform shear rate assumption is verified in the case of simple Newtonian and non-Newtonian fluids, a range of anomalous behavior (apparent slip, shear banding, and fracture) is observed in other systems, including wormlike surfactants, semidilute solutions of 18 MDa polyacrylamide, and dispersed silica in silicone grease. (C) 1997 The Society of Rheology.
引用
收藏
页码:1365 / 1386
页数:22
相关论文
共 41 条
[31]  
Mooney M., 1931, J. Rheol, V2, P210, DOI [10.1122/1.2116364, DOI 10.1122/1.2116364]
[32]   DIRECT DETERMINATION OF APPARENT SLIP FOR A DUCTED FLOW OF POLYACRYLAMIDE SOLUTIONS [J].
MULLERMOHNSSEN, H ;
LOBL, HP ;
SCHAUERTE, W .
JOURNAL OF RHEOLOGY, 1987, 31 (04) :323-336
[33]   NMR INVESTIGATION OF CHAIN DEFORMATION IN SHEARED POLYMER FLUIDS [J].
NAKATANI, AI ;
POLIKS, MD ;
SAMULSKI, ET .
MACROMOLECULES, 1990, 23 (10) :2686-2692
[34]   ASYMPTOTIC ANALYSIS OF THE FINITE CONE-AND-PLATE FLOW OF A NON-NEWTONIAN FLUID [J].
OLAGUNJU, DO .
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS, 1993, 50 (2-3) :289-303
[35]  
Oldroyd J. G., 1956, RHEOLOGY THEORY APPL, P653
[36]   Thixotropic colloidal suspensions and flow curves with minimum: Identification of flow regimes and rheometric consequences [J].
Pignon, F ;
Magnin, A ;
Piau, JM .
JOURNAL OF RHEOLOGY, 1996, 40 (04) :573-587
[37]   NUCLEAR-MAGNETIC-RESONANCE IMAGING OF FLOW FOR A SHEAR-THINNING POLYMER IN CYLINDRICAL COUETTE GEOMETRY [J].
ROFE, CJ ;
LAMBERT, RK ;
CALLAGHAN, PT .
JOURNAL OF RHEOLOGY, 1994, 38 (04) :875-887
[38]  
SHAWFEH ESG, 1996, ANNU REV FLUID MECH, V28, P129
[39]   SPIN DIFFUSION MEASUREMENTS: SPIN ECHOES IN THE PRESENCE OF A TIME-DEPENDENT FIELD GRADIENT [J].
STEJSKAL, EO ;
TANNER, JE .
JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (01) :288-+
[40]  
Walters K., 1968, POLYMER SYSTEMS DEFO, P211