exo-binding of Na+ between two fused calix[4]arenes and endo binding of Na+ within the calix[4]arene cones in the disodium salt of 1,3-dimethyl ether p-tert-butylcalix[4]arene

被引：31

作者：

Dubberley, SR ^{[1
]}

Blake, AJ ^{[1
]}

Mountford, P ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 17期

关键词：

D O I：

10.1039/a701639e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 1,3-dimethyl ether p-tert-butylcalix[4]arene (H2L) with sodium hydride in tetrahydrofuran affords the dimeric metallocalixarene species [Na2L](2) which possesses a novel structure in which the Na+ ions are coordinated in two very different environments.

引用

页码：1603 / 1604

页数：2

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