Dual p- and n-type doping in an acid sensitive alternating bi(ethylenedioxythiophene) and pyridine polymer

被引:72
作者
Irvin, DJ [1 ]
DuBois, CJ [1 ]
Reynolds, JR [1 ]
机构
[1] Univ Florida, Ctr Macromol Sci & Engn, Dept Chem, Gainesville, FL 32611 USA
关键词
D O I
10.1039/a904584h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Poly[2,5-bis(3,4-ethylenedioxy-2-thienyl)pyridine] exhibits multi-color electrochromism via easily accesible p- and n-type doping, and can be switched between a pale blue reduced state, a red neutral state, and a blue-purple oxidized state.
引用
收藏
页码:2121 / 2122
页数:2
相关论文
共 15 条
[1]   Reversible n-doping of poly(nonylbithiazole) and oligomeric model compounds. Application as a Li battery electrode [J].
Curtis, MD ;
Cheng, HT ;
Nanos, JI ;
Nazri, GA .
MACROMOLECULES, 1998, 31 (01) :205-207
[2]   Electropolymerization of acenaphtho[1,2-k]fluoranthene derivatives:: Formation of a new conductive electroactive electrochromic hydrocarbon ladder polymer [J].
Debad, JD ;
Bard, AJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (10) :2476-2477
[3]   Stability of n-type doped conducting polymers and consequences for polymeric microelectronic devices [J].
deLeeuw, DM ;
Simenon, MMJ ;
Brown, AR ;
Einerhand, REF .
SYNTHETIC METALS, 1997, 87 (01) :53-59
[4]   SYNTHESIS, SPECTROELECTROCHEMISTRY AND APPLICATION IN ELECTROCHROMIC DEVICES OF AN N-DOPABLE AND P-DOPABLE CONDUCTING POLYMER [J].
FERRARIS, JP ;
HENDERSON, C ;
TORRES, D ;
MEEKER, D .
SYNTHETIC METALS, 1995, 72 (02) :147-152
[5]   Low-oxidation-potential conducting polymers: alternating substituted para-phenylene and 3,4-ethylenedioxythiophene repeat units [J].
Irvin, JA ;
Reynolds, JR .
POLYMER, 1998, 39 (11) :2339-2347
[6]   Conducting copolymers of pyridine with thiophene, N-methylpyrrole, and selenophene [J].
Jenkins, IH ;
Salzner, U ;
Pickup, PG .
CHEMISTRY OF MATERIALS, 1996, 8 (10) :2444-2450
[7]   Extended heterocyclic systems .2. The synthesis and characterisation of (2-furyl)pyridines, (2-thienyl)pyridines, and furan-pyridine and thiophene-pyridine oligomers [J].
Jones, RA ;
Civcir, PU .
TETRAHEDRON, 1997, 53 (34) :11529-11540
[8]   NEW PI-CONJUGATED HETEROAROMATIC ALTERNATIVE COPOLYMERS WITH ELECTRON-DONATING THIOPHENE OR FURAN UNITS AND ELECTRON-WITHDRAWING QUINOXALINE UNITS - PREPARATION BY PALLADIUM-CATALYZED POLYCONDENSATION AND CHARACTERIZATION OF THE COPOLYMERS [J].
KANBARA, T ;
MIYAZAKI, Y ;
YAMAMOTO, T .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1995, 33 (06) :999-1003
[9]   Synthetic principles for bandgap control in linear pi-conjugated systems [J].
Roncali, J .
CHEMICAL REVIEWS, 1997, 97 (01) :173-205
[10]  
Skotheim T.A., 1998, Handbook of Conducting Polymer