Does Gd@C82 have an anomalous endohedral structure?: Synthesis and single crystal X-ray structure of the carbene adduct

被引：74

作者：

Akasaka, Takeshi ^{[1
]}

Kono, Takayoshi ^{[1
]}

Takematsu, Yuji ^{[1
]}

Nikawa, Hidefumi ^{[1
]}

Nakahodo, Tsukasa ^{[1
]}

Wakahara, Takatsugu ^{[1
]}

Ishitsuka, Midori O. ^{[1
]}

Tsuchiya, Takahiro ^{[1
]}

Maeda, Yutaka ^{[2
]}

Liu, Michael T. H. ^{[3
]}

Yoza, Kenji ^{[5
]}

Kato, Tatsuhisa ^{[4
]}

Yamamoto, Kazunori ^{[6
]}

Mizorogi, Naomi ^{[7
]}

Slanina, Zdenek ^{[1
]}

Nagase, Shigeru ^{[7
]}

机构：

[1] Univ Tsukuba, Ctr Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan

[2] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan

[3] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada

[4] Josai Univ, Dept Chem, Sakado, Saitama 1718501, Japan

[5] Bruker AXS KK, Yokohama, Kanagawa 2210022, Japan

[6] Japan Atom Energy Agcy, Tokai, Ibaraki 3191100, Japan

[7] Natl Inst Nat Sci, Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 39期

关键词：

D O I：

10.1021/ja802156n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report here the results on single crystal X-ray crystallographic analysis of the Gd@C-82 carbene adduct (Gd@C-82(Ad), Ad = adamantylidene). The Gd atom in Gd@C-82(Ad) is located at an off-centered position near a hexagonal ring in the C-2V-C-82 cage, as found for M@C-82 (M = Sc and La) and La@C-82(Ad). Theoretical calculation also confirms the position of the Gd atom in the X-ray crystal structure.

引用

页码：12840 / +

页数：3

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