Structural characterization of Y@C82

被引：38

作者：

Feng, L

Wakahara, T

Tsuchiya, T

Maeda, Y

Lian, YF

Akasaka, T ^{[1
]}

Mizorogi, N

Kobayashi, K

Nagase, S

Kadish, KM

机构：

[1] Univ Tsukuba, Ctr Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan

[2] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan

[3] Inst Mol Sci, Dept Theoret Mol Sci, Okazaki, Aichi 4448585, Japan

[4] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

CHEMICAL PHYSICS LETTERS | 2005年 / 405卷 / 4-6期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/j.cplett.2005.02.032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cation and anion Of Y@C-82 were prepared by controlled potential electrolysis, and their stabilities were investigated by spectroscopic methods. The anion is found to be much more stable than the cation under an air atmosphere. The cage structure of Y@C-82 was determined by observing the C-13 NMR spectrum of the stable diamagnetic anion. It is confirmed that Y@C-82 has C-2v symmetry. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：274 / 277

页数：4

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