Structural determination of the La@C82 isomer

被引:111
作者
Akasaka, T
Wakahara, T
Nagase, S
Kobayashi, K
Waelchli, M
Yamamoto, K
Kondo, M
Shirakura, S
Maeda, Y
Kato, T
Kako, M
Nakadaira, Y
Gao, X
Van Caemelbecke, E
Kadish, KM
机构
[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan
[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[3] Tokyo Metropolitan Univ, Dept Chem, Grad Sch Sci, Hachioji, Tokyo 1920397, Japan
[4] Bruker Japan, Tsukuba, Ibaraki 3050051, Japan
[5] Power Reactor & Nucl Fuel Dev Corp, Tokai, Ibaraki 3191100, Japan
[6] Univ Electrocommun, Dept Appl Phys & Chem, Chofu, Tokyo 1828585, Japan
[7] Univ Houston, Dept Chem, Houston, TX 77204 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 2001年 / 105卷 / 15期
关键词
D O I
10.1021/jp003930d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
stable diamagnetic monoanion of the La@C-82 isomer was electrochemically prepared and isolated in order to disclose its cage symmetry. By measuring the C-13 NMR spectrum of the anion, it was determined for the first time that the isomer has C-s symmetry, as was also confirmed by density functional calculations.
引用
收藏
页码:2971 / 2974
页数:4
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