Interpenetrating copper-silver cyanometallate networks: Polymorphs and topological isomers

被引：37

作者：

Chippindale, AM ^{[1
]}

Cheyne, SM ^{[1
]}

Hibble, SJ ^{[1
]}

机构：

[1] Univ Reading, Sch Chem, Reading RG6 6AD, Berks, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 48期

关键词：

copper; cyanides; framework structures; polymorphism; silver;

D O I：

10.1002/anie.200502372

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Caught in the net: A series of mixed copper(I)-silver(I) cyanide complexes of the form A[Ag2Cu(CN)4] (A = K, Rb, Cs) have been found to form interpenetrating layer structures and three-dimensional networks (see picture). Two different forms of the Rb and Cs compounds are observed, which are both topological isomers and polymorphs. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7942 / 7946

页数：5

共 27 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2]

[Anonymous], 1996, CAMERON

[3] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part II. Analysis of the Inorganic Crystal Structure Database (ICSD) [J].

Baburin, IA ;

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2452-2474

[4]

Batten S.R., 1998, ANGEW CHEM, V110, P1558, DOI DOI 10.1002/(SICI)1521-3757(19980605)110:11<1558::AID-ANGE1558>3.0.CO

[5]

2-7

[6] Topology of interpenetration [J].

Batten, SR .

CRYSTENGCOMM, 2001, (18)

[7] Topological isomerism in coordination polymers [J].

Blake, AJ ;

Brooks, NR ;

Champness, NR ;

Crew, M ;

Deveson, A ;

Fenske, D ;

Gregory, DH ;

Hanton, LR ;

Hubberstey, P ;

Schröder, M .

CHEMICAL COMMUNICATIONS, 2001, (16) :1432-1433

[8] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database [J].

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

CRYSTENGCOMM, 2004, 6 :377-395

[9] Polycatenation, polythreading and polyknotting in coordination network chemistry [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :247-289

[10] Coordination networks from the self-assembly of silver salts and the linear chain dinitriles NC(CH2)nCN (n = 2 to 7):: a systematic investigation of the role of counterions and of the increasing length of the spacers [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM ;

Rizzato, S .

CRYSTENGCOMM, 2002, 4 :413-425

← 1 2 3 →