Electrochemical approaches to alleviation of the problem of carbon dioxide accumulation

被引:104
作者
Sánchez-Sánchez, CM
Montiel, V
Tryk, DA
Aldaz, A
Fujishima, A
机构
[1] Univ Alicante, Dept Quim Fis, Grp Electroquim Aplicada, E-03080 Alicante, Spain
[2] Univ Tokyo, Sch Engn, Dept Appl Chem, Tokyo 1138656, Japan
关键词
D O I
10.1351/pac200173121917
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrochemical reduction of CO2 which includes a number of different specific approaches, may show promise as a means to help slow down the accumulation of this greenhouse gas in the atmosphere, Two types of approaches are examined briefly here. First, CO2 can be used as a reagent in the electrocarboxylation reaction to produce organic carboxylic acids, for example. the pharmaceutical ibuprofen. Second, CO2 can be converted to a fuel, either directly or via synthesis gas. The latter can be produced with reasonably good energy efficiency in a gas-diffusion, electrode-based cell even at present with existing electrocatalysts. Oxygen gas is produced as a by-product. Further work is needed to improve the selectivity and efficiency in this and other approaches.
引用
收藏
页码:1917 / 1927
页数:11
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