Electrochemical approaches to alleviation of the problem of carbon dioxide accumulation

被引:104
作者
Sánchez-Sánchez, CM
Montiel, V
Tryk, DA
Aldaz, A
Fujishima, A
机构
[1] Univ Alicante, Dept Quim Fis, Grp Electroquim Aplicada, E-03080 Alicante, Spain
[2] Univ Tokyo, Sch Engn, Dept Appl Chem, Tokyo 1138656, Japan
关键词
D O I
10.1351/pac200173121917
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrochemical reduction of CO2 which includes a number of different specific approaches, may show promise as a means to help slow down the accumulation of this greenhouse gas in the atmosphere, Two types of approaches are examined briefly here. First, CO2 can be used as a reagent in the electrocarboxylation reaction to produce organic carboxylic acids, for example. the pharmaceutical ibuprofen. Second, CO2 can be converted to a fuel, either directly or via synthesis gas. The latter can be produced with reasonably good energy efficiency in a gas-diffusion, electrode-based cell even at present with existing electrocatalysts. Oxygen gas is produced as a by-product. Further work is needed to improve the selectivity and efficiency in this and other approaches.
引用
收藏
页码:1917 / 1927
页数:11
相关论文
共 73 条
[11]   REACTIONS AT THE COUNTER ELECTRODE IN ELECTROREDUCTIONS UNDER APROTIC CONDITIONS IN ONE-COMPARTMENT CELLS [J].
ENGELS, R ;
SMIT, CJ ;
VANTILBORG, WJM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (06) :492-493
[12]   NICKEL CATALYZED ELECTROSYNTHESIS OF ANTI-INFLAMMATORY AGENTS .1. SYNTHESIS OF ARYL-2 PROPIONIC ACIDS, UNDER GALVANOSTATIC CONDITIONS [J].
FAUVARQUE, JF ;
JUTAND, A ;
FRANCOIS, M .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1988, 18 (01) :109-115
[13]   ELECTROCATALYZED CARBOXYLATION OF ORGANIC HALIDES BY A COBALT-SALEN COMPLEX [J].
FOLEST, JC ;
DUPRILOT, JM ;
PERICHON, J ;
ROBIN, Y ;
DEVYNCK, J .
TETRAHEDRON LETTERS, 1985, 26 (22) :2633-2636
[14]   ELECTROCHEMICAL CARBOXYLATION OF SOME HETEROAROMATIC-COMPOUNDS [J].
FUCHS, P ;
HESS, U ;
HOLST, HH ;
LUND, H .
ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1981, 35 (03) :185-192
[15]   ELECTROCATALYTIC REDUCTION OF CO2 BY NICKEL(II) CYCLAM - STUDY OF THE REDUCTION-MECHANISM ON MERCURY BY CYCLIC VOLTAMMETRY, POLAROGRAPHY AND ELECTROCAPILLARITY [J].
FUJIHIRA, M ;
HIRATA, Y ;
SUGA, K .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 292 (1-2) :199-215
[16]   ELECTROREDUCTION OF CARBON-DIOXIDE BY METAL PHTHALOCYANINES [J].
FURUYA, N ;
KOIDE, S .
ELECTROCHIMICA ACTA, 1991, 36 (08) :1309-1313
[17]   High performance Ru-Pd catalysts for CO2 reduction at gas-diffusion electrodes [J].
Furuya, N ;
Yamazaki, T ;
Shibata, M .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 431 (01) :39-41
[18]   SOLUBILITY AND ELECTROCHEMICAL DETERMINATION OF CO2 IN SOME DIPOLAR APROTIC-SOLVENTS [J].
GENNARO, A ;
ISSE, AA ;
VIANELLO, E .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 289 (1-2) :203-215
[19]   THE ELECTROLYTIC REDUCTION OF CARBON-DIOXIDE AND MONOXIDE FOR THE PRODUCTION OF CARBOXYLIC-ACIDS [J].
GOODRIDGE, F ;
PRESLAND, G .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1984, 14 (06) :791-796
[20]  
Halmann M.M., 1999, GREENHOUSE GAS CARBO