Synthesis and characterization of SnOx/Al2O3 derived gel catalysts

被引：7

作者：

Gomez, R

Sanchez, J

Silva, R

Lopez, T

机构：

[1] Universidad Autonoma Metropolitana-Iztapalapa, Department of Chemistry, Mexico 09340 D.F.

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1996年 / 59卷 / 02期

关键词：

tin-alumina support; sol-gel derived alumina; isopropanol dehydration; tin-alumina acidity;

D O I：

10.1007/BF02068120

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

SnOx/Al2O3 catalysts were prepared by the sol-gel method using as starting reactants aluminium-tri-s-butoxide and (i) tetrabutyltin, (ii) tin tetrachloride and (iii) tin tetra-t-amyloxide. The gel derived catalysts show acidities of 0.72, 1.08 and 1.05 mu mol NH3/m(2) and BET areas of 91, 112 and 189 m(2)/g. The activity and selectivity pattern for isopropanol decomposition were found to depend strongly on the tin precursor used.

引用

页码：247 / 251

页数：5