Radical chemistry based on (+)-cis-pinononic and (+)-cis-pinonic acids

被引：12

作者：

Barton, DHR ^{[1
]}

Fontana, G ^{[1
]}

机构：

[1] TEXAS A&M UNIV, DEPT CHEM, COLLEGE STN, TX 77843 USA

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 10期

关键词：

D O I：

10.1080/00397919608003550

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A high yield method for the preparation of (+)-cis-pinononic acid starting from the inexpensive (+)-alpha-pinene has been developed. The capture of the cyclobutyl radical from decarboxylation of (+)-cis-pinononic acid has been investigated. Moreover the radical decarboxylation of (+)-cis-pinonic acid to the corresponding nor-alkane was studied.

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页码：1953 / 1968

页数：16

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