9,10,19,20-Tetraarylporphycenes

被引：48

作者：

Anju, K. S. ^{[1
]}

Ramakrishnan, S. ^{[1
]}

Thomas, Ajesh P. ^{[1
]}

Suresh, Eringathodi ^{[2
]}

Srinivasan, Alagar ^{[1
]}

机构：

[1] NIIST CSIR, Chem Sci & Technol Div, Photosci & Photon Sect, Trivandrum 695019, Kerala, India

[2] CSMCRI CSIR, Analyt Sci Discipline, Bhavnagar 364002, Gujarat, India

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 24期

关键词：

D O I：

10.1021/ol802351r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

meso-Tetraarylporphycenes, structural isomers of meso-tetraarylporphyrins, were synthesized by the acid-catalyzed oxidative coupling reaction for the first time which is an alternative synthetic methodology to the traditional McMurry coupling reaction. The structure of the macrocycle and Ni(II) complex are characterized by single-crystal X-ray diffraction analyses where both form 1-D supramolecular assembly.

引用

页码：5545 / 5548

页数：4

共 24 条

[1] Diethyl 2,7-dibromo-4H,5H-thieno[3,2-b:4,5-b′]dipyrrole-3,6-dicarboxylate:: A key intermediate for a diversity oriented synthesis of 2,7,12,17-tetraarylporphycenes [J].

Arad, O ;

Morros, J ;

Batllori, X ;

Teixidó, J ;

Nonell, S ;

Borrell, JI .

ORGANIC LETTERS, 2006, 8 (05) :847-850

[2]

Cañete M, 2000, ANTI-CANCER DRUG DES, V15, P143

[3] ELECTROCHEMICAL, UV/VISIBLE, AND EPR CHARACTERIZATION OF METALLOPORPHYCENES CONTAINING FIRST-ROW TRANSITION-METALS [J].

DSOUZA, F ;

BOULAS, P ;

AUKAULOO, AM ;

GUILARD, R ;

KISTERS, M ;

VOGEL, E ;

KADISH, KM .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (46) :11885-11891

[4]

Fowler CJ, 2002, CHEM-EUR J, V8, P3485, DOI 10.1002/1521-3765(20020802)8:15<3485::AID-CHEM3485>3.0.CO

[5]

2-9

[6] A non-tetradecarboxylative synthesis of 2,7,12,17-tetraphenylporphycene [J].

Gavalda, A ;

Borrell, JI ;

Teixido, J ;

Nonell, S ;

Arad, O ;

Grau, R ;

Cañete, MC ;

Juarranz, A ;

Villanueva, A ;

Stockert, JC .

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2001, 5 (12) :846-852

[7] REDOX PROPERTIES OF PORPHYCENES AND METALLOPORPHYCENES AS COMPARED WITH PORPHYRINS [J].

GISSELBRECHT, JP ;

GROSS, M ;

KOCHER, M ;

LAUSMANN, M ;

VOGEL, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (23) :8618-8620

[8]

Guilard R, 1995, SYNTHESIS-STUTTGART, P1480

[9] 1ST REVERSIBLE ELECTROGENERATION OF TRIPLY OXIDIZED NICKEL PORPHYRINS AND PORPHYCENES - FORMATION OF NICKEL(III) PI-DICATIONS [J].

KADISH, KM ;

VANCAEMELBECKE, E ;

BOULAS, P ;

DSOUZA, F ;

VOGEL, E ;

KISTERS, M ;

MEDFORTH, CJ ;

SMITH, KM .

INORGANIC CHEMISTRY, 1993, 32 (20) :4177-4178

[10] MU-OXODIIRON(III) COMPLEXES OF PORPHYCENES [J].

LAUSMANN, M ;

ZIMMER, I ;

LEX, J ;

LUEKEN, H ;

WIEGHARDT, K ;

VOGEL, E .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (07) :736-739

← 1 2 3 →