Infrared spectrum of the bis-(1,10-phenanthroline) Cu(I) and Cu(II) perchlorate complexes

被引：58

作者：

CamposVallette, MM

Clavijo, RE

Mendizabal, F

Zamudio, W

Baraona, R

Diaz, G

机构：

[1] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,DEPT QUIM BAS,SANTIAGO,CHILE

[2] UNIV PLAYA ANCHA,FAC CIENCIAS,DEPT QUIM,VALPARAISO,CHILE

来源：

VIBRATIONAL SPECTROSCOPY | 1996年 / 12卷 / 01期

关键词：

copper complexes; bis-(1,10-phenanthroline);

D O I：

10.1016/0924-2031(96)00012-4

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

FT-IR spectra of the title compounds and derivatives were measured in the range 4000-120 cm(-1). A complete cm experimental spectral assignment has been performed. A simplified normal coordinate treatment orientates some assignment of frequencies in the low energy region. Bands at ca. 420 and 300 cm(-1) are ascribed to the nu Cu-N modes. A stability order of the Cu(I) complexes is proposed on the basis of their Cu-N frequency values.

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页码：37 / 44

页数：8

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