First synthesis of sulfines by direct oxidation of xanthates

被引：11

作者：

Marriere, E ^{[1
]}

Chevrie, D ^{[1
]}

Metzner, P ^{[1
]}

机构：

[1] UNIV CAEN,ISMRA,UNITE MIXTE CNRS,LAB CHIM MOL & THIOORGAN,F-14050 CAEN,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 14期

关键词：

D O I：

10.1039/a703706f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sulfines are formed by the reaction of xanthates with m-chloroperoxybenzoic acid; they are spontaneously converted at ambient temperature to thiocarbonates and dithioperoxycarbonates unless kinetic steric protection provided by a substituent makes the sulfine stable.

引用

页码：2019 / 2020

页数：2

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