A dinuclear zinc(II) complex of 2,6-bis[((2-hydroxybenzyl) (2-pyridylmethyl)amino)methyl]-4-methylphenol derived from bis(acetylacetonato)zinc(II)

被引：15

作者：

Adams, H ^{[1
]}

Bradshaw, D ^{[1
]}

Fenton, DE ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 01期

关键词：

crystal structure; phenolato-bridge; zinc(II) complex;

D O I：

10.1016/S1387-7003(01)00338-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the symmetrical proligand H3L with bis(acetylacetonato)zinc(II) has given the homodinuclear complex [Zn2L(acac)] . CH3CN in which one of the pendant phenolato groups functions as a bridge for the dinuclear zinc centre. The complex crystallises in the triclinic space group P-1, with unit cell parameters a = 10.0250(11) Angstrom, b = 10.6132(13) Angstrom. c = 19.139(2) Angstrom, alpha = 80.418(2)0, beta = 75.792(2)degrees, gamma = 84.532(2)degrees. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：12 / 14

页数：3

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