Preparation of helicenes through olefin metathesis

被引：124

作者：

Collins, Shawn K. ^{[1
]}

Grandbois, Alain ^{[1
]}

Vachon, Martin P. ^{[1
]}

Cote, Julie ^{[1
]}

机构：

[1] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 18期

关键词：

arenes; helical structures; helicenes; microwave irradiation; olefin metathesis;

D O I：

10.1002/anie.200504150

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Metathesis with a twist! A ring-closing-metathesis strategy has been developed for the preparation of various substituted [5]helicene motifs and [6]- and [7]helicenes. The two optimized protocols include one method that utilizes the Grubbs second-generation catalyst under microwave-irradiation conditions and another that employs a modified Grubbs-Hoveyda catalyst at 40°C in a sealed reaction vessel. (Mes = mesityl). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2923 / 2926

页数：4

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