Thermophysical Properties of N-Octyl-3-methylpyridinium Tetrafluoroborate

被引:42
作者
Bandres, Isabel [1 ]
Giner, Beatriz [1 ]
Artigas, Hector [1 ]
Lafuente, Carlos [1 ]
Royo, Felix M. [1 ]
机构
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ Quim Fis, E-50009 Zaragoza, Spain
关键词
TEMPERATURE IONIC LIQUIDS; PHYSICOCHEMICAL PROPERTIES; SURFACE TENSIONS; VISCOSITY; CONDUCTIVITY; PRESSURES; FLUIDS; CATION; ANION;
D O I
10.1021/je8002095
中图分类号
O414.1 [热力学];
学科分类号
摘要
Density, speed of sound, refractive index, surface tension, isobaric molar heat capacity, and kinematic viscosity of the room-temperature ionic liquid N-octyl-3-methylpyridinium tetrafluoroborate have been measured over a temperature range. From the results, coefficients of thermal expansion, molar refractions, and dynamic viscosities have been derived. The properties are discussed further in terms of the effect of the variations of the alkyl chain length on the pyridinium cation.
引用
收藏
页码:236 / 240
页数:5
相关论文
共 19 条
[1]   Application of hole theory to the viscosity of ionic and molecular liquids [J].
Abbott, AP .
CHEMPHYSCHEM, 2004, 5 (08) :1242-1246
[2]   Thermophysic comparative study of two isomeric pyridinium-based ionic liquids [J].
Bandres, Isabel ;
Giner, Beatriz ;
Artigas, Hector ;
Royo, Felix M. ;
Lafuente, Carlos .
JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (10) :3077-3084
[3]   Phase transition and decomposition temperatures, heat capacities and viscosities of pyridinium ionic liquids [J].
Crosthwaite, JM ;
Muldoon, MJ ;
Dixon, JK ;
Anderson, JL ;
Brennecke, JF .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2005, 37 (06) :559-568
[4]   On the properties of 1-butyl-3-methylimidazolium octylsulfate ionic liquid [J].
Davila, Maria J. ;
Aparicio, Santiago ;
Alcalde, Rafael ;
Garcia, Begona ;
Leal, Jose M. .
GREEN CHEMISTRY, 2007, 9 (03) :221-232
[5]   Volumetric behaviour of the environmentally compatible lubricants pentaerythritol tetraheptanoate and pentaerythritol tetranonanoate at high pressures [J].
Fandiño, O ;
Pensado, AS ;
Lugo, L ;
López, ER ;
Fernández, J .
GREEN CHEMISTRY, 2005, 7 (11) :775-783
[6]   Thermophysical properties of imidazolium-based ionic liquids [J].
Fredlake, CP ;
Crosthwaite, JM ;
Hert, DG ;
Aki, SNVK ;
Brennecke, JF .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (04) :954-964
[7]   Surface tensions of imidazolium based ionic liquids: Anion, cation, temperature and water effect [J].
Freire, Mara G. ;
Carvalho, Pedro J. ;
Fernandes, Ana M. ;
Marrucho, Isabel M. ;
Queimada, Antonio J. ;
Coutinho, Joao A. P. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 314 (02) :621-630
[8]   Analysis of recent measurements of the viscosity of glasses [J].
Fulcher, GS .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1925, 8 (06) :339-355
[9]   Surface tensions for isomeric chlorobutanes with isomeric butanols [J].
Giner, B ;
Cea, P ;
López, MC ;
Royo, MM ;
Lafuente, C .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 275 (01) :284-289
[10]   Surface tension measurements of N-alkylimidazolium ionic liquids [J].
Law, G ;
Watson, PR .
LANGMUIR, 2001, 17 (20) :6138-6141