Electrochemical synthesis of new benzodifurans

被引：14

作者：

Davarani, Saied Saeed Hosseiny ^{[1
]}

Fakhari, Ali Reza ^{[1
]}

Fumani, Neda Sheijooni ^{[1
]}

Kalate-bojdi, Majid ^{[1
]}

机构：

[1] Shahid Beheshti Univ, Fac Sci, Dept Chem, Gc Tehran 1983963113, Iran

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2008年 / 10卷 / 11期

关键词：

Electrochemical synthesis; Cyclic voltammetry; Benzodifuran; Chloranilic acid; Catechol; Controlled-potential coulometry;

D O I：

10.1016/j.elecom.2008.08.052

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrochemical oxidation of catechol (1a) and 3-methyl-catechol (1b) has been studied in the presence of chloranilic acid (3) as a nucleophile in aqueous solution using cyclic voltammetry and controlled-potential coulometry. In this work, we proposed a novel mechanism for the electrode process and derived variety of products with good yield and purity using controlled-potential electrochemical oxidation at a graphite electrode in a two compartment cell. (c) 2008 Elsevier B.V. All rights reserved.

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收藏

页码：1765 / 1768

页数：4

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