Fine structure of the two-photon photoemission from benzene adsorbed on Cu(111)

被引：31

作者：

Munakata, T ^{[1
]}

Sakashita, T ^{[1
]}

Tsukakoshi, M ^{[1
]}

Nakamura, J ^{[1
]}

机构：

[1] SCI UNIV TOKYO,SHINJUKU KU,TOKYO 162,JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 271卷 / 4-6期

关键词：

D O I：

10.1016/S0009-2614(97)00458-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two-photon photoemission (2PPE) spectroscopy has been applied to benzene adsorbed on a Cu(111) surface. With laser light in the 3.7 to 4.3 eV photon energy region, 2PPE occurs through benzene-induced excited states which are about 1 eV above the Fermi level. The excited state is considered to be the lowest triplet state of adsorbed benzene. The spectrum shows a progression of sharp peaks of less than 0.2 eV width, each separated by about 0.2 eV. The widths of the peaks indicate that the lifetimes of the excited and ionic states are both longer than 3 fs.

引用

页码：377 / 380

页数：4

共 16 条

[11] DIRECT OBSERVATION OF INTERSYSTEM CROSSING IN BENZENE BY LASER PHOTOELECTRON-SPECTROSCOPY [J].