Selective metal substitution for the preparation of heterobimetallic microporous coordination polymers

被引：92

作者：

Caskey, Stephen R.

Matzger, Adam J. ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem & Macromol Sci, Ann Arbor, MI 48109 USA

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 18期

关键词：

D O I：

10.1021/ic8007427

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The designed synthesis of heterobimetallic microporous coordination polymers (MCPs) is reported by a strategy employing the selective replacement of a single metal in homometallic MCPs with two unique metal coordination environments: octahedral and tetrahedral. This strategy is successful in the preparation of six mixed-metal MCPs, where Co/Zn and Ni/Zn versions of MOF-4 MOF-39, and a Zn-BTEC MCP are reported.

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页码：7942 / 7944

页数：3

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