Concomitant and controllable chiral/racemic polymorphs: From achirality to isotactic, syndiotactic, and heterotactic chirality

被引:103
作者
Li, Xin-Zhi [1 ]
Li, Mian [1 ]
Li, Zhen [1 ]
Hou, Jin-Zhang [1 ]
Huang, Xiao-Chun [1 ]
Li, Dan [1 ]
机构
[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
chirality; helical structures; polymorphism; solvent effects; supramolecular chemistry;
D O I
10.1002/anie.200801481
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Making a resolution: A unique example of chiral/racemic polymorphs, which are obtained from achiral components (see picture), illustrates the evolution in chirality from partial to complete spontaneous resolution, and the phenomenon of supramolecular isotactic, syndiotactic, and heterotactic chirality. (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6371 / 6374
页数:4
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